Natalia Jiménez来自一个混血家庭，她的爸爸是西班牙歌手，她的妈妈则是来自于葡萄牙。早在2007年，Natalia就获得了一次在葡萄牙歌手Ednita Nazario的《Real》专辑中演出的机会。
In 2007, Natalia had a participation (featuring) in the album "Real" of the Puerto Rican singer Ednita Nazario, performed a duet song "No", (composed by Armando Avila and self Natalia). This song only appears on the album Ednita Nazario.
The Best Thing About Me Is You" is Ricky Martin's new single with the original English version of the song features singer Joss Stone, while its Spanish version, "Lo Mejor De Mi Vida Eres Tú", replaces Stone's vocals with Natalia Jiménez.
On November 12, 2010, after appearing and performing at the 2010 Latin Grammys with Ricky Martin, Natalia announced her solo album and said she hopes to release her first single in January. She also announced that the band, La Quinta Estacion was not broken up and that she and Angel Reyero, her bandmate, were focusing on solo projects. She said "The band is still there, everything is still there, one day we will release another album [as La Quinta Estacion]"